期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 352, 期 17, 页码 2918-2922出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000409
关键词
aldehydes; alpha-amino nitriles; cyanation; cyanohydrins; imines; tin
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan
A novel reaction involving cyano transfer from benzophenone cyanohydrin to aldehydes and imines was realized by using dibutyltin dimethoxide as a catalyst. Various cyanohydrins and alpha-amino nitriles were obtained in moderate to high yields by this reaction. Ketimines also showed remarkable reactivity as cyano acceptors under conventional reaction conditions. This catalytic reaction was further applied to a three-component condensation reaction of aldehydes, aniline, and benzophenone cyanohydrin in the presence of Drierite (R).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据