4.7 Article

Cyclobutenes as Isolable Intermediates in the Gold(I)-Catalysed Cycloisomerisation of 1,8-Enynes

期刊

ADVANCED SYNTHESIS & CATALYSIS
卷 351, 期 3, 页码 379-386

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900056

关键词

[2+2]cycloaddition; cyclobutenes; gold; homogeneous catalysis

向作者/读者索取更多资源

The gold(I)-catalysed isomerisation of 1,8-enynes allows the efficient synthesis of functionalised bicyclo[5.2.0]nonenes. Notably, these cyclobutenes derivatives can be isolated as reactive intermediates that could undergo subsequent gold(I)-catalysed transformations such as isomerisation, fragmentation or ene reaction to furnish more structurally complex products. This study also provides useful information related to the mechanism leading to metathesis-type derivatives, examples of which were shown to be produced, in the present case, by a gold(I)-catalysed ring fragmentation of the cyclobutene moiety.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据