期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 351, 期 16, 页码 2702-2708出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900442
关键词
2-alkynylbenzaldoximes; bismuth triflate; isocyanides; N-(isoquinolin-1-yl)formamides; silver triflate
资金
- National Natural Science Foundation of China [20772018]
- Science and Technology Commission of Shanghai Municipality [09JC14049]
- Program for New Century Excellent Talents in University [NCET-07-0208]
An efficient tandem reaction of 2-alkynylbenzaldoximes with isocyanides co-catalyzed by silver triflate and bismuth triflate has been developed, which gives rise to the unexpected N-(isoquinolin-1-yl)formamides in good to excellent yields. The iodo- and bromo-containing products could be obtained as well by variation of the reaction conditions.
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