期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 351, 期 10, 页码 1629-1636出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900074
关键词
catalysis in water; hemispherical diphosphites; hydroformylation; large bite angles; micelles; surfactants
The combination of calixarene-derived surfactants and neutral rhodium complexes containing a hemispherical 1,3-calix-diphosphite ligand led to efficient catalysts for the hydroformylation of octene and other olefins in water. While the surfactants allowed the formation of micelles that dissolve both the catalyst and the alkene, thereby resulting In high olefin:rhodium ratios. the diphosphite provided a tight envelope about the catalytic centre able to drive the reaction towards the linear aldehydes. Best results in the hydroformylation of I-octene were obtained when using [tetra(p-sulfonato)]-(tetra-n-butoxy)-calix[4]arene as surfactant. With this additive remarkable linear to branched aldehyde ratios of up to 62 were obtained, the corresponding activities being higher than those observed when operating in an organic solvent [turnover frequencies (TOFs) up to 630 mol(converted 1-octene)mol(Rh) (1).h(-1)].
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