期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 351, 期 18, 页码 3077-3082出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900579
关键词
2-amino-2-chromenes; heterocycles; Michael addition; organocatalysis
资金
- National Natural Science Foundation of China [20902083, 20672101]
- Province Natural Science Foundation [Y4090082]
- Zhejiang Noraml University
The asymmetric synthesis of functionalized 2-amino-2-chromene derivatives with high enantioselectivities via one-pot tandem reactions of functionalized alpha,beta-unsaturated ketones with malononitrile catalyzed by 9-amino-9-deoxyepiquinine (1a) in combination with (R)-1,1'-binaphth-2,2'-diyl hydrogen phosphate (1c) is reported for the first time.
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