期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 351, 期 3, 页码 363-366出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200800634
关键词
aldehydes; beta-aryloxy primary alcohols; asymmetric catalysis; dynamic kinetic resolution; ruthenium
资金
- National Natural Science Foundation of China [20532010, 20572049, 20721062]
- Major Basic Research Development program [2006CB806106]
- Ministry of Education of China [B06005]
- Merck Research Laboratories
A catalytic enantioselective hydrogenation of racemic alpha-aryloxy aldehydes via dynamic kinetic resolution has been developed by using (diamine)(spirodiphosphine)ruthenium(II) chloride [RuCl2(SDPs)(diamine)] catalysts. Employing this new reaction system a variety of optically active beta-aryloxy primary alcohols were synthesized in high yields and moderate to good enantioselectivities.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据