期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 351, 期 1-2, 页码 71-77出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200800522
关键词
catalysis; C-C coupling; Mizoroki-Heck reaction; palladium; thiadiazolidines
资金
- Loughborough University
- Research Councils UK
We herein report a highly active catalyst system using for the first time a thiadiazolidine 1-oxide as a ligand for palladium in the Mizoroki-Heck reaction. Excellent yields of stilbenes derived from aryl iodides and bromides have been achieved using as little as 0.00002 mol% catalyst. The ligand/palladium system can be stored as a stock solution open to air at room temperature with no observable loss of activity for a period of several weeks/months.
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