期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 351, 期 9, 页码 1233-1237出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900106
关键词
aerobic oxidation; amines; bimetallic catalysts; carbonylation; nanoparticles; ureas
资金
- Korean Government (MOEHRD) [KRF-2008-341-C00022]
- Korea Science and Engineering Foundation (KOSEF)
- Korea Government (MEST) [R11-2005-065]
- Brain Korea 21 for fellowships
An environmentally friendly oxidative carbonylation of aliphatic and aromatic primary amines to ureas has been successfully achieved in the presence of a catalytic amount of cobalt/rhodium heterobimetallic nanoparticles without any promoters. The catalyst system could be reused with only a slight loss of catalytic activity.
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