期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 351, 期 17, 页码 2817-2821出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200900594
关键词
amination; amino acids; asymmetric catalysis; organocatalysis; quaternary stereocenters
资金
- MEXT, Japan [19020006]
- JSPS Research Fellowship
- Grants-in-Aid for Scientific Research [19020006] Funding Source: KAKEN
An enantioselective electrophilic amination of alpha-substituted cyanothioacetates with azodicarboxylate is demonstrated using an axially chiral guanidine as a chiral Bronsted base catalyst. The corresponding product, having a quaternary stereogenic center at the alpha-carbon atom, is formed in excellent enantioselectivity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据
分享论文
