期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 351, 期 1-2, 页码 276-282出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200800608
关键词
asymmetric aldol reactions; catalyst recycling; ionic-tagged catalysts; organic catalysis; solvent-free conditions
资金
- University of Bologna
The installation of an imidazolium tag via acetate connection to the C-4 of cis-4-hydroxy-L-proline provides a highly efficient catalyst for the direct asymmetric aldol reaction, that works in a remarkably low catalyst loading (0.1 mol%) affording TONS up to 930 in the case of electron-poor aromatic aldehydes with ee up to > 99%.
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