期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 350, 期 13, 页码 1975-1978出版社
WILEY-BLACKWELL
DOI: 10.1002/adsc.200800338
关键词
alcohols; alkenes; hydrogen transfer; organocatalysis; ruthenium
资金
- EPSRC
A ruthenium-catalysed oxidation of alcohols by hydrogen transfer has been coupled with organocatalysed condensations using pyrrolidine or piperidine, to give alpha,beta-unsaturated esters and nitroalkenes. Reactions proceed with high (E)-selectivity and provide an efficient and straightforward route alpha,beta-unsaturated compounds.
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