期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 350, 期 16, 页码 2566-2574出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200800455
关键词
catalyst recycling; nanoparticles; organic-inorganic hybrid composites; palladium; sol-gel processes; Suzuki-Miyaura reaction
资金
- MEC of Spain [CTQ2006-04204/BQU]
- Consolider Ingenio 2010 [CSD2007-00006]
- Generalitat de Catalunya [SGR2005-00305]
- CNANO
The systems formed by palladium acetate [Pd(OAC)(2)] and hybrid silica materials prepared by sol-gel from monosilylated imidazolium, and disilylated dihydroimidazolium salts show catalytic activity in Suzuki-Miyaura cross-couplings with challenging aryl bromides and chlorides. They are very efficient as recoverable catalysts with aryl bromides. Recycling is also possible with aryl chlorides, although with lower conversions. In situ formation of palladium nanoparticles has been observed in recycling experiments.
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