期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 350, 期 16, 页码 2617-2630出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200800413
关键词
cycloaddition; 1,5-enynes; gold; homogeneous catalysis; polycycles
The gold(I)-catalyzed isomerization of readily available 1,8-dien-4-ynes allows the rapid construction of a variety of synthetically useful bicyclo[4.3.0]nonenes by a stereoselective sequence involving a [4+2] annelation/nucleophilic addition process.
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