4.7 Article

Palladium-Catalyzed Heck Coupling-Hydrogenation: Highly Efficient One-Pot Synthesis of Dibenzyls and Alkyl Phenyl Esters

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ADVANCED SYNTHESIS & CATALYSIS
卷 350, 期 16, 页码 2544-2550

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200800460

关键词

dibenzyls; molecular hydrogen; nanocrystalline magnesium oxide; one-pot synthesis; palladium(0)

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An efficient method for the synthesis of industrially important dibenzyls and alkyl phenyl esters via sequential Heck coupling and hydrogenation of the alkenyl double bond in one pot with a single recyclable catalyst under mild conditions has been realised. The catalyst was recovered by simple filteration and reused for several cycles with consistent activity.

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