期刊
ADVANCED MATERIALS
卷 26, 期 41, 页码 7027-+出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201401672
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资金
- National Natural Science Foundation of China [21272093]
- Specialized Research Fund for the Doctoral Program of Higher Education of China [20120061120117]
- Innovation Program of the State Key Laboratory of Supramolecular Structure and Materials
Low-density, solid-state, porous supramolecular organic frameworks are constructed using pillarenes. The frameworks have a honeycomb-like structure, permanent porosity, high thermal stability, and selective and reversible sorption properties toward CO2. The exceptionally selective CO2-sorption properties (375/1, 339/1) of one framework over N-2 and CH4 indicate potential applications in CO2-capture for post-combustion power plants and natural gas sweetening.
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