4.8 Article

Closely Interconnected Network of Molybdenum Phosphide Nanoparticles: A Highly Efficient Electrocatalyst for Generating Hydrogen from Water

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ADVANCED MATERIALS
卷 26, 期 32, 页码 5702-+

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WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201401692

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资金

  1. National Natural Science Foundation of China [21175129]
  2. National Basic Research Program of China [2011CB935800]

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A closely interconnected network of MoP nanoparticles (MoP-CA2) with rich nanopores, large specific surface area, and high conductivity can function as a highly active non-noble metal catalyst for electrochemically generating hydrogen from acidic water. The network exhibits nearly 100% Faradaic efficiency and needs over-potentials of 125 and 200 mV to attain current densities of 10 and 100 mA cm(-2), respectively. The catalytic activity is maintained for at least 24 h.

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