期刊
ADVANCED MATERIALS
卷 27, 期 2, 页码 234-239出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201403299
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资金
- Fluid Interface Reactions, Structures and Transport (FIRST) Center, an Energy Frontier Research Center - US Department of Energy, Office of Science, Office of Basic Energy Sciences
- US Department of Energy, Office of Basic Energy Sciences, Division of Materials Science and Engineering
Soluble porous coordination polymers from mechanochemical synthesis are presented through a coordination polymerization between highly contorted, rigid tetraphenol and a broad variety of transition metal ions. These polymers can be easily cast as metal-containing films or freestanding membranes. Importantly, as-made coordination polymers are highly active and stable in the aerobic oxidation of allylic C-H bonds.
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