4.8 Article

Monolayer MoS2 Films Supported by 3D Nanoporous Metals for High-Efficiency Electrocatalytic Hydrogen Production

期刊

ADVANCED MATERIALS
卷 26, 期 47, 页码 8023-+

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WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201403808

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资金

  1. JST-CREST Phase Interface Science for Highly Efficient Energy Utilization, JST, Japan
  2. World Premier International (WPI) Research Center Initiative for Atoms, Molecules and Materials, MEXT, Japan
  3. National Science Foundation of China

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The edge-free monolayer MoS2 films supported by 3D nanoporous gold show high catalytic activities towards hydrogen evolution reaction (HER), originating from large out-of-plane strains that are geometrically required to manage the 3D curvature of bicontinuous nano porosity. The large lattice bending leads to local semiconductor-to-metal transition of 2H MoS2 and the formation of catalytically active sites for HER.

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