4.8 Article

Water-Free Titania-Bronze Thin Films with Superfast Lithium-Ion Transport

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ADVANCED MATERIALS
卷 26, 期 43, 页码 7365-7370

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201401757

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资金

  1. Ford Motor Company under a University Research Proposal grant
  2. National Science Foundation [CBET-1159240, DMR-0723032]
  3. US Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [DE-FG02-07ER46416]
  4. Div Of Chem, Bioeng, Env, & Transp Sys
  5. Directorate For Engineering [1159240] Funding Source: National Science Foundation

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Using pulsed laser deposition, TiO2-B and its recently discovered variant Ca:TiO2-B (CaTi5O11) are synthesized as highly crystalline thin films for the first time by a completely water-free process. Significant enhancement in the Li-ion battery performance is achieved by manipulating the crystal orientation of the films, used as anodes, with a demonstration of extraordinary structural stability under extreme conditions.

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