期刊
ADVANCED MATERIALS
卷 26, 期 21, 页码 3526-3531出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201305783
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资金
- European Community [NMP3-SL-2009-228631]
- Italian Programma Operativo Nazionale Ricerca e Competitivita [PON01_01840]
- EPSRC [EP/G01244X, EP/G062129/1]
- EPSRC [EP/G062129/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/G062129/1] Funding Source: researchfish
A highly gas permeable polymer with exceptional size selectivity is prepared by fusing triptycene units together via a polymerization reaction involving Troger's base formation. The extreme rigidity of this polymer of intrinsic microporosity (PIM-Trip-TB) facilitates gas permeability data that lie well above the benchmark 2008 Robeson upper bounds for the important O-2/N-2 and H-2/N-2 gas pairs.
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