4.8 Article

Ionic Liquid Enabled FeS2 for High-Energy-Density Lithium-Ion Batteries

期刊

ADVANCED MATERIALS
卷 26, 期 43, 页码 7386-7392

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201402103

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资金

  1. Boulder Ionics Corporation through the Membrane Science, Engineering and Technology (MAST) Center at CU-Boulder, an NSF Industry-University Cooperative Research Center
  2. National Science Foundation [IIP-1152040]
  3. National Science Foundation (NSF) [CHE-1231048]
  4. Direct For Mathematical & Physical Scien
  5. Division Of Materials Research [1231048] Funding Source: National Science Foundation
  6. Div Of Industrial Innovation & Partnersh
  7. Directorate For Engineering [1152040, 1034720] Funding Source: National Science Foundation

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High-energy-density FeS2 cathodes enabled by a bis(trifluoromethanesulfonyl)imide (TFSI-) anion-based room temperature ionic liquid (RTIL) electrolyte are demonstrated. A TFSI-based ionic liquid (IL) significantly mitigates polysulfide dissolution, and therefore the parasitic redox shuttle mechanism, that plagues sulfur-based electrode chemistries. FeS2 stabilization with a TFSI--based IL results in one of the highest energy density cathodes, 542 W h kg(-1) (normalized to cathode composite mass), reported to date.

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