期刊
ADVANCED MATERIALS
卷 25, 期 44, 页码 6334-6365出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201301752
关键词
nanodielectrics; polymer nanocomposites; dielectric property; energy storage; energy density
类别
资金
- NSF of China [51073015, 50977001]
- NSF of Beijing City [2122040]
- Ministry of Sciences and Technology of China through the China-Europe International Incorporation Project [2010DFA51490]
- State Key Laboratory of Power Transmission Equipment AMP
- System Security and New Technology [2007DA10512712406]
Study of flexible nanodielectric materials (FNDMs) with high permittivity is one of the most active academic research areas in advanced functional materials. FNDMs with excellent dielectric properties are demonstrated to show great promise as energy-storage dielectric layers in high-performance capacitors. These materials, in common, consist of nanoscale particles dispersed into a flexible polymer matrix so that both the physical/chemical characteristics of the nanoparticles and the interaction between the nanoparticles and the polymers have crucial effects on the microstructures and final properties. This review first outlines the crucial issues in the nanodielectric field and then focuses on recent remarkable research developments in the fabrication of FNDMs with special constitutents, molecular structures, and microstructures. Possible reasons for several persistent issues are analyzed and the general strategies to realize FNDMs with excellent integral properties are summarized. The review further highlights some exciting examples of these FNDMs for power-energy-storage applications.
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