期刊
ADVANCED MATERIALS
卷 25, 期 16, 页码 2362-2367出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201204015
关键词
polymer solar cells; electron spin resonance; hole accumulation; performance deterioration; organic interfaces
类别
资金
- Japan Society for the Promotion of Science (JSPS) [24560004, 22340080]
- JST, PRESTO
- Grants-in-Aid for Scientific Research [24560004] Funding Source: KAKEN
A clear correlation between the number of accumulated holes (N-spin) in poly(3-hexylthiophene) (P3HT) and the deterioration of the performance is observed in polymer solar cells under simulated solar irradiation. The sites of hole accumulation with deep trapping levels are formed at the interfaces between P3HT:[6,6]-phenyl C-61-butyric acid methyl ester (PCBM) and poly(3,4-ethylenedioxythiophene): poly(4-styrenesulfonate) (PEDOT:PSS) layers.
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