期刊
ADVANCED MATERIALS
卷 25, 期 14, 页码 2024-2028出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201203815
关键词
photopolymerization; CuAAC; temporal control; high glass transition polymer; triazole linkage
类别
资金
- National Science Foundation [CHE 1214109]
- Industry/University Cooperative Research Center for Fundamentals and Applications of Photopolymerizations
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1214109] Funding Source: National Science Foundation
The first bulk photopolymerization of multifunctional alkyne and azide monomers using the CuAAC reaction is successfully carried out from low molecular weight, nonviscous monomer resins. Compared to other traditional step-growth bulk photo polymerization, this approach readily provides crosslinked, high glass transition temperature polymers that incorporate triazole linkages throughout the polymer structure with great temporal control.
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