期刊
ADVANCED MATERIALS
卷 25, 期 12, 页码 1796-1800出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201204831
关键词
azobenzene; photomechanical bending; isomerization in crystals
类别
资金
- NSERC Canada
- Canadian Foundation for Innovation
Pseudostilbene-type single crystals exhibit ubiquitous, fast, and reversible photomechanical motion under visible-light irradiation. Push-pull substituents impart extremely rapid switching using just one wavelength of light by shortening the lifetime of the cis-form. This results in a bending motion in the microsecond regime. The influence of crystal density, thickness, and molecular orientation on optimization of the photomechanical effect is investigated.
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