期刊
ADVANCED MATERIALS
卷 26, 期 5, 页码 752-757出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201303643
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- BASF SE
- Fonds der Chemischen Industrie
The aqueous calcium carbonate system is rigorously investigated with respect to ionic activity. Ideal treatment is found to be a good approximation at relevant concentrations. The data further show that bound CaCO3 species cannot be regarded as inactive during nucleation but rather appear to play a key role in the phase-separation process, and that amorphous calcium carbonate (ACC) can be precipitated from much lower levels of supersaturation than previously believed.
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