4.8 Article

A Spirobifluorene-Based Polymer of Intrinsic Microporosity with Improved Performance for Gas Separation

期刊

ADVANCED MATERIALS
卷 24, 期 44, 页码 5930-+

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201202393

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资金

  1. European Community [NMP3-SL-2009-228631]
  2. EPSRC [EP/G01244X, EP/H024034/1]
  3. EPSRC [EP/G01244X/1, EP/H024034/1] Funding Source: UKRI
  4. Engineering and Physical Sciences Research Council [EP/H024034/1, EP/G01244X/1] Funding Source: researchfish

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A highly gas-permeable polymer with enhanced selectivities is prepared using spirobifluorene as the main structural unit. The greater rigidity of this polymer of intrinsic microporosity (PIM-SBF) facilitates gas permeability data that lie above the 2008 Robeson upper bound, which is the universal performance indicator for polymer gas separation membranes.

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