期刊
ADVANCED MATERIALS
卷 24, 期 7, 页码 886-+出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201103340
关键词
stimuli-responsive materials; polymer electrolytes; redox electrodes
类别
资金
- Sandia LDRD
- 3M Non-Tenured Faculty
- U.S. Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000]
A thermally responsive copolymer is designed to modulate the properties of an electrolyte solution. The copolymer is prepared using pNIPAM, which governs the thermal properties, and acrylic acid, which provides the electrolyte ions. As the polymer undergoes a thermally activated phase transition, the local environment around the acid groups is reversibly switched, decreasing ion concentration and conductivity. The responsive electrolyte is used to control the activity of redox electrodes with temperature.
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