期刊
ADVANCED MATERIALS
卷 25, 期 1, 页码 120-124出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201202638
关键词
monolayers; conjugated oligomers; fluorescent sensors; energy transfer; thin films
类别
资金
- NSF [CHE-0547895]
Surface-immobilized monolayers of fluorescent molecular sensors consisting of a short conjugated oligo(p-phenylene ethynylene) core end-capped with an acceptor fluorophore (analyte receptor) display significant signal amplification due to enhanced intermolecular energy transfer within the monolayer. This general phenomenon offers a superior platform for designing ratiometric fluorescent sensors. An example of how this can be used to convert a narrow-range threshold fluorescent pH indicator (fluorescein) to a broad-range ratiometric fluorescent chemosensor is described.
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