期刊
ADVANCED MATERIALS
卷 23, 期 40, 页码 4690-+出版社
WILEY-BLACKWELL
DOI: 10.1002/adma.201102552
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资金
- Chinese National Programs for Fundamental Research and Development [2011CB612207]
- Beijing Natural Science Foundation [2112006]
- German Research Foundation [SPP 1473-SO 1075/1-1]
A universal mechanism that controls the zero thermal expansion (ZTE) behavior of the antiperovskite manganese nitrides is discovered. Modulating the Mn occupancy at its lattice sites leads to a drastic change in the thermal expansion behavior. The Mn site occupancy can be reduced by nanostructuring the material, generating a form of giant ZTE.
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