期刊
ADVANCED MATERIALS
卷 22, 期 17, 页码 1915-+出版社
WILEY-BLACKWELL
DOI: 10.1002/adma.200903934
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资金
- CMU
- AFOSR [9550-07-1-0245]
Thiolate-protected Au-n clusters are exploited as homogeneous and supported catalysts for two chemical processes: i) the selective oxidation of styrene by O-2 to benzaldehyde and ii) the chemoselective hydrogenation of alpha,beta-unsaturated ketone to alpha,beta-unsaturated alcohol. The results demonstrate that a quantum-size effect in Au-n clusters plays a critical role in their catalysis. This work highlights the importance of pursuing quantum-sized gold clusters for catalysis. [GRAPHICS] .
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