4.8 Article

Temperature-Controlled Transitions Between Glass, Liquid, and Gel States in Dense p-NIPA Suspensions

期刊

ADVANCED MATERIALS
卷 22, 期 31, 页码 3441-+

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200904189

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资金

  1. NSF [DMR-0602684]
  2. Harvard MRSEC [DMR-0213805]
  3. Junta de Andalucia [FQM-3116]
  4. University of Almeria
  5. Division Of Materials Research
  6. Direct For Mathematical & Physical Scien [820484] Funding Source: National Science Foundation

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The elastic modulus, G'(p), of concentrated suspensions of thermoresponsive microgel particles highlights transitions between glassy, liquid-like, and gel-like behavior as the temperature is varied Approaching the low critical solution temperature of the particles, T-c approximate to 29 degrees C, the material undergoes solid-to-liquid transitions even above random close packing and irrespective of particle concentration

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