期刊
ADVANCED MATERIALS
卷 21, 期 22, 页码 2339-2344出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200803554
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资金
- Waseda University Global COE Program from MEXT Japan
- [17067017]
- [19105003]
- [19655043]
- Grants-in-Aid for Scientific Research [21550120] Funding Source: KAKEN
Radical polymers are aliphatic or nonconjugated polymers bearing organic robust radicals as pendant groups per repeating unit. A large population of the radical redox sites allows the efficient redox gradient-driven electron transport through the polymer layer by outer-sphere self-exchange reactions in electrolyte solutions. The radical polymers are emerging as a new class of electroactive materials useful for various kinds of wet-type energy storage, transport, and conversion devices. Electric-field-driven charge transport by hopping between the densely populated radical sites is also a remarkable aspect of the radical polymers in the solid state, which leads to many dry-type devices such as organic memories, diodes, and switches.
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