4.8 Article

Improved Thermoelectric Properties of Cu-Doped Quaternary Chalcogenides of Cu2CdSnSe4

期刊

ADVANCED MATERIALS
卷 21, 期 37, 页码 3808-3812

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WILEY-BLACKWELL
DOI: 10.1002/adma.200900409

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资金

  1. National 973 Program of China [2007CB936704]
  2. National Science Foundation of China [50772123]
  3. Science and Technology Commission of Shanghai and Science [0752 nm016]
  4. Innovation Group of international Cooperation Plan [50821004]
  5. US National Science Foundation [DMR-07-05054, DMR-05-20020]

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The chalcopyrite-like structure Of Cu(2)MSnQ(4) is an ordered tetrahedral array of flattened CuQ(4) and undistorted MQ(4) and SnQ(4), with a low lattice thermal conductivity. The [Cu2O4] tetrahedral layers are electrically conducting, and the [SnMQ(4)] layers are electrically insulating.

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