4.8 Article

Calamitic Liquid-Crystalline Elastomers Swollen in Bent-Core Liquid-Crystal Solvents

期刊

ADVANCED MATERIALS
卷 21, 期 16, 页码 1622-+

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WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200802739

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资金

  1. NSF [DMR 0606357, DMR-0606160]
  2. Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy
  3. ONR [N00014-07-1-0440]

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The swelling of calamitic liquid crystal elastomers (LCEs) with bent-core mesogens is investigated in the isotropic phase of both materials. The swelling magnitude and dynamics are determined and fitted with a dual exponential. The host LCEs imbibe bent-core molecules up to 30-40 mol%. The swollen elastomers exhibit nematic phases, with some possessing a lower temperature smectic phase.

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