4.8 Article

Calcite Growth in Hydrogels: Assessing the Mechanism of Polymer-Network Incorporation into Single Crystals

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ADVANCED MATERIALS
卷 21, 期 4, 页码 470-+

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WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200801498

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资金

  1. J. D. Watson Investigator Program (NYSTAR) [C050017]
  2. Cornell Center for Materials Research (CCMR)
  3. Materials Research Science and Engineering Center of the National Science Foundation [DMR 0520404]

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Calcite crystals grown in agarose hydrogels incorporate the gel network while retaining their single-crystal nature. The amount of gel network that is incorporated is determined by two competing factors: crystallization pressure promotes the exclusion of the gel network, while faster growth rates favor its incorporation.

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