期刊
ADVANCED MATERIALS
卷 20, 期 17, 页码 3331-+出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200800506
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资金
- Royal Society-Wolfson Trust Research Merit Award
Colloidal vinvl polymer-silica nanocomposite particles are synthesized with very high silica aggregation efficiencies via aqueous emulsion using a cationic azo initiator in the presence of a glycerol-functionalized ultrafine aqueous silica sol as the sole stabilizing agent (see scheme). The protocol is surfactant-free and requires neither auxiliary comonomer nor nonaqueous co-solvent. The particles are film-forming at ambient temperature, yielding highly transparent films containing up to 39% silica by mass.
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