期刊
ADVANCED MATERIALS
卷 20, 期 11, 页码 2225-+出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200702268
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Polystannanes, organometallic polymers with a backbone of covalently connected tin atoms, can be regarded as molecular metal wires surrounded by a jacket of organic matter (see figure). Polymers that differ in the length of the alkyl side groups feature reversible phase transitions into liquid-crystalline states (some of them even below room temperature) and are oriented either parallel or perpendicular to external driving forces, depending on the length of the alkyl substituents.
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