期刊
ADVANCED FUNCTIONAL MATERIALS
卷 28, 期 36, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201802945
关键词
bipolar hosts; deep-blue devices; high color purity CIE x ,y (<= 0.15); high external quantum efficiency (EQE); low-roll off
类别
资金
- National Research Foundation (NRF) by the Ministry of Science, ICT & Future Planning (MSIP) of Korea [2013M3C1A3065522, 2016M3A7B4909246]
Recently, bipolar host materials are the most promising candidates for achieving high performance phosphorescent organic light-emitting diodes (PHOLEDs) in order to maximize recombination efficiency. However, the development of host material with high triplet energy (E-T) is still a great challenge to date to overcome the limitations associated with the present PHOLEDs. Herein, a highly efficient donor-pi-acceptor (D-pi-A) type bipolar host (4'-(9H-carbazol-9-yl)-2,2'-dimethyl-[1,1'-biphenyl]-4-yl)diphenylphosphine oxide (m-CBPPO) comprising of carbazole, 2,2'-dimethylbiphenyl and diphenylphosphoryl as D-pi-A unit, respectively, is developed. Interestingly, a high E-T of 3.02 eV is observed for m-CBPPO due to highly twisted conformation. Furthermore, the new host material is incorporated in PHOLEDs as emissive layer with a new carbene type Ir(cb)(3) material as a deep-blue emitter. The optimized devices show an excellent external quantum efficiency (EQE) of 24.8% with a notable Commission internationale de l'eclairage (x, y) <= 0.15, (0.136, 0.138) and high electroluminescence performance with extremely low efficiency roll-off. Overall, the above EQE is the highest reported for deep-blue PHOLEDs with very low efficiency roll-off and also indicate the importance of appropriate host for the development of high performance deep-blue PHOLEDs.
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