期刊
ADVANCED FUNCTIONAL MATERIALS
卷 24, 期 31, 页码 4969-4977出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201400484
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资金
- Office of Naval Research [N00014-10-1-0393]
- Carderock Division of the Naval Surface Warfare Center's In-house Laboratory Independent Research Program [0601152N]
- Division of Materials Science and Engineering, US Department of Energy, Office of Basic Energy Sciences
The excellent properties exhibited by monolayer graphene have spurred the development of exfoliation techniques using bulk graphite to produce large quantities of pristine monolayer sheets. Development of simple chemistry to exfoliate and intercalate graphite and graphite mimics in large quantities is required for numerous applications. To determine the macroscopic behavior of restacked, exfoliated bulk materials, a systematic approach is presented using a simple, redox-liquid sonication process along to obtain large quantities of 2D and 3D hexagonally layered graphite, molybdenum disulfide, and boron nitride, which are subsequently characterized to observe chemical and structural changes. For MoS2 sonicated with the antioxidant sodium bisulfite, results from Raman spectroscopy, X-ray diffraction, and electron microscopy indicate the presence of distorted phases from different polymorphs, and apparent nanotube structures in the bulk, restacked powder. Furthermore, using thermograviemtric analysis, the antioxidant enhances the resistance to oxidative degradation of MoS2, upon thermal treatment up to 900 degrees C. The addition of the ionic antioxidant decreased dispersion stability in non-polar solvent, suggesting decreased compatibility with non-polar systems. Using simple chemical methods, the ability to generate tailored multidimensional layered materials with unique macroscopic properties is critical for numerous applications, including electrical devices, reinforced polymer composites, lithium-ion capacitors, and chemical sensing.
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