期刊
ADVANCED FUNCTIONAL MATERIALS
卷 24, 期 15, 页码 2155-2162出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201303273
关键词
metal sulfides; hollow spheres; microspheres; supercapacitors; dye-sensitized solar cells
类别
资金
- A*STAR SERC grant [1021700144]
- Singapore National Research Foundation
- MPA [23/04.15.03 RDP 020/10/113]
We demonstrate in this paper facile synthesis of CoS2 and NiS2 hollow spheres with various interiors through a solution-based route. The obtained CoS2 microspheres constructed by nanosheets display a three-dimensional architecture with solid, yolk-shell, double-shell, and hollow interiors respectively, with continuous changes in specific surface areas and pore-size distributions. Especially, the CoS2 hollow spheres demonstrate excellent supercapacitive performance including high specific capacitance, good charge/discharge stability and long-term cycling life, owing to the greatly improved faradaic redox reaction and mass transfer. Furthermore, CoS2 hollow spheres exhibit superior electrocatalytic activity for disulfide/thiolate (T-2/T-) redox electrolyte in dye-sensitized solar cells (DSCs). Therefore, this work provides a promising approach for the design and synthesis of structure tunable materials with largely enhanced supercapacitor behavior, which can be potentially applied in energy storage devices.
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