期刊
ADVANCED FUNCTIONAL MATERIALS
卷 23, 期 43, 页码 5420-5428出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201300699
关键词
doping-free OLEDs; phosphorescent OLEDs; triplet-triplet annihilation; triplet-polaron quenching; platinum(II) bis(pyridyl)triazolate; fast phosphors
类别
资金
- National Science Foundation [CHE-0911690, CMMI-0963509, CHE-0840518]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0911690] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0840518] Funding Source: National Science Foundation
By introducing a neat Pt(II)-based phosphor with a remarkably short decay lifetime, a simplified doping-free phosphorescent organic light-emitting diode (OLED) with a forward viewing external quantum efficiency (EQE) and power efficiency of 20.3 +/- 0.5% and 63.0 +/- 0.4 lm W-1, respectively, is demonstrated. A quantitative analysis of how triplet-triplet annihilation (TTA) and triplet-polaron annihilation (TPA) affect the device EQE roll-off at high current densities is performed. The contributions from loss of charge balance associated with charge leakage and field-induced exciton dissociation are found negligible. The rate constants k(TTA) and k(TPA) are determined by time-resolved photoluminescence experiments of a thin film and an electrically-driven unipolar device, respectively. Using the parameters extracted experimentally, the EQE is modeled versus electric current characteristics of the OLEDs by taking both TTA and TPA into account. Based on this model, the impacts of the emitter lifetime, quenching rate constants, and exciton formation zone upon device efficiency are analyzed. It is found that the short lifetime of the neat emitter is key for the reduction of triplet quenching.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据