期刊
ADVANCED FUNCTIONAL MATERIALS
卷 21, 期 2, 页码 356-363出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201001446
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资金
- Engineering and Physical Sciences Research Council (EPSRC) [EP/F023200]
- Research Councils UK (RCUK)
- Engineering and Physical Sciences Research Council [EP/F023200/1] Funding Source: researchfish
- EPSRC [EP/F023200/1] Funding Source: UKRI
Organic field-effect transistors (OFETs) are used to investigate the evolution of the solid-state microstructure of blends of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C-61-butyric acid methyl ester (PC61BM) upon annealing. Changes in the measured field-effect mobility of holes and electrons are shown to reveal relevant information about the phase-segregation in this system, which are in agreement with a eutectic phase behavior. Using dual-gate OFETs and in-situ measurements, it is demonstrated that the spatialand time-dependence of microstructural changes in such polymer: fullerene blend films can also be probed. A percolation-theory-based simulation is carried out to illustrate how phase-segregation in this system is expected to lead to a substantial decrease in the electron conductivity in an OFET channel, in qualitative agreement with experimental results.
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