期刊
INORGANICA CHIMICA ACTA
卷 431, 期 -, 页码 176-183出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2014.12.022
关键词
Molybdenum; Tridentate Schiff-base ligands; Epoxidation; Organic solvent-free; Catalysis
资金
- Centre National de la Recherche Scientifique (CNRS)
- Institut Universitaire de France (IUF)
- Universidad Nacional Autonoma de Mexico
- Universite Paul Sabatier
- Institut Universitaire Technologique
- China Scholarship Council [201208370239]
- CONACYT [318435]
Molybdenum complexes of type [MoO2L](n) (L = tridentate ONO Schiff base ligands based on the salicylidene-2-aminophenolato structure) have been synthesized and used as catalysts for the solvent-free epoxidation of olefins. The effect of donor (diethylamino) and/or acceptor (nitro) substituents has been studied. (C) 2015 Elsevier B.V. All rights reserved.
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