期刊
INORGANIC CHEMISTRY
卷 54, 期 22, 页码 10539-10541出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b02348
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The reaction of uranyl ions with azelaic or dodecanedioic acids under solvohydrotherrnal conditions leads to crystallization of anionic dinudear cage compounds with [M(bipy/phen)(3)](2+) counterions (M = 3d-block cation), while the smaller suberic acid yields heterometallic metallacycles. Complexes with the longer aliphatic chains are the first triple-stranded helicates reported in actinide chemistry.
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