期刊
INORGANIC CHEMISTRY
卷 54, 期 10, 页码 4862-4868出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b00435
关键词
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资金
- National University of Singapore (NUS) [R-279-000-369-133]
- Singapore Ministry of Education (MOE AcRF Tier 1) [R-279-000-410-112]
- Singapore Ministry of Education (MOE AcRF Tier 2) [R-279-000-429-112]
- National University of Singapore (CENGas) [R-261-508-001-646]
Developing a general and economicallye viable approach for the large-scale Synthesis of water-stable Metal organic frameworks (MOFs) With repeatable quality remains the key step for their massive production and commercialization. We herein report a green (aqueous solutions), mild (100 degrees C, 1 atm), and scalable able (can be up to kilograms) modulated hydrothermal (MHT) synthesis of UiO-66; an iconic MOF that has been widely studied recently for its high water stability: More importantly, the MHT synthetic approach can be applied to synthesize other water-stable MOFs with structures identical to UiO-66, such as UiO-66-(F)(4), UiO-66-(OCH2CH3)(2), and UiO-66-(COOH)(4), which cannot be obtained via the traditional solvothermal method. Their performance in postcombustion CO2 capture has also been evaluated. Our MINT approach has clearly depicted a roadmap for the facile synthesis of zirconium based water stable MOFs to facilitate their massive production and commercialization.
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