期刊
INORGANIC CHEMISTRY
卷 54, 期 9, 页码 4345-4350出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b00041
关键词
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资金
- 973 Key Program of the MOST [2012CB821705]
- National Natural Science Foundation of China [21373221, 21221001, 91122027, 51172232, 21403236]
- Chinese Academy of Sciences [KJCX2-YW-319, KJCX2-EW-H01]
- Natural Science Foundation of Fujian Province [2012J06006, 2006L2005]
An effective strategy to synthesize multifunctional materials is the incorporation of functional organic moieties and metal oxide clusters via self-assembly. A rare multifunctional radical-doped zinc-based host guest crystalline material was synthesized with a fast-responsive reversible ultraviolet visible light photochromism, photocontrolled tunable luminescence, and highly selective photocatalytic oxidation of benzylic alcohols as a result of blending of distinctively different functional components, naphthalenediimide tectons, and polyoxometalates (POMs). It is highly unique to link pi-zelectron-deficient organic tectons and POMs by unusual POMs anion-pi interactions, which are not only conducive to keeping the independence of each component but also effectively promoting the charge transfer or exchange among the components to realize the fast-responsive photochromism, photocontrolled tunable luminescence, and photocatalytic activity.
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