期刊
INORGANIC CHEMISTRY
卷 54, 期 9, 页码 4377-4381出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b00194
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资金
- National Natural Science Foundation of China [51272231, 51229201]
- Program for Innovative Research Team in University of Ministry of Education of China [IRT13R54]
- Welch Foundation [AX-1730]
- Zhejiang Provincial Natural Science Foundation of China [LZ15E020001]
A new organic hexacarboxylic acid, 5,5',5 ''-(9H-carbazole-3,6,9-triyl)triisophthalic acid (H(6)CTIA), was developed to construct its first microporous metal organic framework (MOP), Cu-6(CTIA)(2) (ZJU-70). With open metal sites and suitable pore sizes, this MOP exhibits high acetylene and methane storage capacities at room temperature.
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