期刊
JOURNAL OF ENVIRONMENTAL QUALITY
卷 39, 期 4, 页码 1349-1358出版社
AMER SOC AGRONOMY
DOI: 10.2134/jeq2009.0298
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资金
- Deutsche Forschungsgemeinschaft (DFG) [W1601/2]
- Earth System Sciences Research Center of the Johannes Gutenberg University Mainz, Germany
Although polycyclic aromatic hydrocarbons (PAHs) have been extensively studied. the knowledge of their oxygen-containing derivatives and metabolites (OPAHs) in sods is limited We modified and tested an existing analytical protocol involving pressurized liquid extraction of soil followed by fractionation of target compounds into PAHs and OPAHs on a silica gel column and gas chromatography/mass spectrometry-based separation and quantification Polycyclic aromatic hydrocarbons and carbonyl-OPAHs were quantified directly after separation on silica gel columns, and hydroxyl/carboxyl-OPAHs were quantified after silylation with N,O-bis(trimethylsilyl)trifluoroacetamide. Recoveries between 78 and 97% (relative standard deviation [RSD], 5-12%) were obtained for six carbonyl-OPAHs, whereas 1,2-acenaphthenequinone and 1,4-naphthoquinone showed lower recoveries of 34 and 44% (RSD, 19 and 28%, respectively) Five hydroxyl/carboxyl-OPAHs had recoveries between 36 and 70% (RSD, 13-46%), six others had between 2 and 7% (RSD, 8-25%). and nine were lost in sample preparation Lamas of detection ranged from 0 1 to 1.6 ng g(-1) for OPAHs and from 001 to 0 56 ng g(-1) for PAHs The protocol was applied to sods from a former gasworks site, Berlin, an urban sod from Mainz, both in Germany, and a forest soil from near Manaus, Brazil The sums of 34 PAH concentrations were 107,000, 3505, and 21 ng g(-1); those of seven carbonyl-OPAHs were 15,690, 170, and 7 ng g(-1); and those of 11 hydroxyl/carboxyl-OPAHs 518, 36, and 16 ng g(-1) for Berlin, Mainz, and Manaus soils, respectively Several OPAHs were present at concentrations higher than or equal to their parent PAHs, demonstrating the importance of OPAH measurement for the assessment of PAH-related environmental risks
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