期刊
INORGANIC CHEMISTRY
卷 54, 期 16, 页码 8121-8125出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b01371
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The recently developed approach for the rational functionalization of deltahedral nona germanium clusters Ge-9(4-) with three substituents to form Ge9R3- (R = Si(SiMe3)(3)) in large amounts has made the latter a convenient starting material for further reactivity studies. Reported here are the synthesis, structures, and solution studies of two compounds where Ge9R3- are used as ligands to transition metals, [(Ge9R3)Cu-I(Ge9R3)(CuPPh3)-P-I] (1) and [(Ge9R3)Pd (Ge9R3)](2-) (2). The former adds to the families of anionic [(Ge9R3)M-I(Ge9R3)](-) (M-I = Cu, Ag, and Au) as a neutral member and of the neutral [(Ge9R3)M-II(Ge9R3)] (M-II = Zn, Cd, and Hg), while the latter represents the first compound involving a metal from group 10.
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